Synthetic route to meso-tetra hydrocarbyl or substituted...

C - Chemistry – Metallurgy – 07 – D

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C07D 487/22 (2006.01) C07D 207/333 (2006.01)

Patent

CA 2112164

ABSTRACT The hydroxyl group in a pyrrolic compound having in the 2-position thereof a group having the formula R(OH)CH- where R is hydrocarbyl or substituted hydrocarbyl, is replaced by a group, for example a p-nitrobenzoate group, having better leaving properties than those of hydroxyl for a subsequent self-condensation and cyclization of the pyrrolic compound to form a meso-hydrocarbyl or meso-substituted hydrocarbyl porphyrin.

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