Proton conducting polymer electrolyte membrane useful in...

H - Electricity – 01 – M

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H01M 8/10 (2006.01) B01D 67/00 (2006.01) B01D 69/14 (2006.01)

Patent

CA 2697891

The present invention provides an alternate proton conducting polymer electrolyte membrane and a process for the preparation thereof. More particularly the present invention provides a conducting hybrid polymer electrolyte membrane com-prising a stable host polymer and a proton-conducting medium as a guest polymer for its suitability in PEM-based fuel cells. The present invention deals with host polymer, comprising a group of poly (vinyl alcohol), poly (vinyl fluoride), polyethylene oxide, polyethyleneimine, polyethylene glycol, cellulose acetate, polyvinylmethylethyl ether, more preferably polyvinyl alcohol and a guest polymer comprising poly (styrene sulfonic acid), poly(acrylic acid), sulfonated phenolic, polyacrylonitrile, polymethyl acrylate, and quaternary ammonium salt, more preferably poly(styrene sulfonic acid).

L'invention concerne une membrane d'électrolyte polymère conductrice de protons interchangeable et un procédé de préparation de celle-ci. Plus particulièrement, elle concerne une membrane d'électrolyte polymère conductrice hybride qui comprend un polymère hôte stable et un milieu conducteur de protons comme polymère invité, cette membrane convenant pour être utilisée dans des piles à combustible à membrane échangeuse de protons. L'invention concerne un polymère hôte choisi dans le groupe comprenant l'alcool polyvinylique, le polyfluorure de vinyle, le polyoxyde d'éthylène, la polyéthylèneimine, le polyéthylène glycol, l'acétate de cellulose, le polyvinylméthyléthyl éther, de préférence l'acool polyvinylique et un polmère invité choisi dans le groupe comprenant l'acide polystyrène sulfonique, l'acide polyacrylique, un composé phénolique sulfoné, le polyacrylonitrile, le polyacrylate de méthyle et un sel d'ammonium quaternaire, de préférence l'acide polystyrène sulfonique.

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