Electrochemical hydrogen storage alloys and batteries...

H - Electricity – 01 – M

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H01M 4/38 (2006.01) C01B 3/00 (2006.01) C22C 19/03 (2006.01) C22C 23/00 (2006.01) H01M 10/36 (2006.01)

Patent

CA 2191114

An electrochemical hydrogen storage material comprising: (Base Alloy)aMb where, Base Alloy is an alloy of Mg and Ni in a ratio of from about 1:2 to about 2:1, preferably 1:1; M represents at least one modifier element chosen from the group consisting of Co, Mn, Al, Fe, Cu, Mo, W, Cr, V, Ti, Zr, Sn, Th, Si, Zn, Li, Cd, Na, Pb, La, Mm, and Ca: b is greater than 0.5, preferably 2.5, atomic percent and less than 30 atomic percent; and a + b = 100 atomic percent. Preferably, the at least one modifier is chosen from the group consisting of Co, Mn, Al, Fe, and Cu and the total mass of the at least one modifier element is less than 25 atomic percent of the final composition. Most preferably, the total mass of said at least one modifier element is less than 20 atomic percent of the final composition.

Un matériau électrochimique de stockage d'hydrogène comprend: (Alliage de base)¿a?M¿b?. Cet alliage de base est un alliage de Mg et Ni dans un rapport compris entre environ 1:2 et environ 2:1, de préférence 1:1; M représente au moins un élément modifiant choisi dans le groupe constitué par Co, Mn, Al, Fe, Cu, Mo, W, Cr, V, Ti, Zr, Sn Th, Si, Zn, Li, Cd, Na, Pb, La, Mm et Ca; b est supérieur à 0,5, de préférence 2,5, pour-cent atomique et inférieur à 30 pour-cent atomique; et a + b = 100 pour-cent atomique. De préférence, au moins l'élément modifiant est choisi dans le groupe comprenant Co, Mn, Al, Fe et Cu et la masse totale de l'élément modifiant est inférieur à 25 pour-cent atomique de la composition finale. Mieux, la masse totale de l'élément modifiant est inférieure à 20 pour-cent atomique de la composition finale.

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