Improved process for recovery of purified terephthalic acid

C - Chemistry – Metallurgy – 07 – C

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C07C 63/26 (2006.01) C07C 51/43 (2006.01) C07F 9/46 (2006.01)

Patent

CA 2108268

A process is disclosed for preparation of purified terephthalic acid containing 200 ppmw or less of p-toluic acid. A filter cake of purified terephthalic acid is prepared by filtering, under a differential pressure of about or greater than 0.5 psi over the system pressure and a temperature within the range of from about 100 °C to about 205 °C, an aqueous slurry of purified tereph- thalic acid containing a solution of p-toluic acid. The aqueous solution of p- toluic acid remaining in the filter cake of purified ter- ephthalic acid is displaced from the filter cake by water under a pressure gradient over the system pressure at a temperature with- in the range of from about 100 °C to about 205 °C. Pressure flash evaporation of water remaining in the filter cake occurs upon release of the system pressure to lower pressure with consequent lower temperature. The crystalline terephthalic acid product con- taining 200 ppmw or less p-toluic acid can be dried under atmospheric pressure. Purified terephthalic acid is useful for the manu- facture of polyesters from which clothing and related goods are made.

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