Process for the preparation of predominantly unbranched...

C - Chemistry – Metallurgy – 07 – C

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C07C 31/125 (2006.01) C07C 29/141 (2006.01) C07C 29/16 (2006.01) C07C 45/50 (2006.01)

Patent

CA 2111026

Hoechst Aktiengesellschaft, 6230 Frankfurt am Main 80 Abstract For the preparation of predominantly unbranched higher primary alcohols, olefins from the Fischer-Tropsch synthesis are reacted with hydrogen and carbon monoxide in the presence of water and rhodium, in metallic form or as a compound, and a water-soluble phosphine as catalyst. The reaction product obtained is hydrogenated. The water- soluble phosphines employed are compounds whose anion is a phosphine containing at least one sulfonated or carb- oxylated aromatic radical and whose cation is a quater- nary ammonium or phosphonium ion.

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