Preparation of bead-form expandable styrene polymers

C - Chemistry – Metallurgy – 08 – J

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C08J 9/20 (2006.01) C08J 9/22 (2006.01)

Patent

CA 2018278

- 11 - O.Z. 0050/40907 Abstract of the Disclosure: Bead-form expandable styrene polymers are obtained by suspension polymerization of styrene with addition of from 1 to 10 % by weight of C3- to C6-hydrocarbons as blowing agents and, if desired, customary additives, where a) the polymerization is initiated by rapidly heating the polymerization batch to from 80 to 90°C within a maximum of 2 hours, b) subsequently allowing the reaction temperature to increase to from 120°C to 130°C by from 8 to 17°C per hour, and c) the conversion is from 30 to 60 % when 100°C is reached, and d) the conversion is 80 % or more when the maximum temperature is reached, and e) the batch is subsequently kept at from 100 to 130°C until the residual monomer content in the polymer has dropped to less than 0.1 %.

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