Nitrated metalloporphyrins as catalysts for alkane oxidation

Details Nitrated metalloporphyrins as catalysts for alkane oxidation Nitrated metalloporphyrins as catalysts for alkane oxidation

C - Chemistry, Metallurgy

07

C

C07C 29/50 (2006.01) B01J 31/18 (2006.01) C07C 31/02 (2006.01) C07C 35/02 (2006.01) C07C 45/33 (2006.01) C07C 45/34 (2006.01) C07D 487/22 (2006.01) C07F 1/08 (2006.01) C07F 11/00 (2006.01) C07F 13/00 (2006.01) C07F 15/00 (2006.01)

Patent

CA 2077983

ABSTRACT In one embodiment, alkanes are oxidized by contact with oxygen-containing gas in the presence as catalyst of a metalloporphyrin in which hydrogen atoms in the porphyrin ring have been replaced with one or more nitro groups. Hydrogen atoms in the porphyrin may also be substituted with halogen atoms. In another embodiment, new compositions of matter comprise nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or .beta.-pyrrolic positions. DRJ0624F.drj ADM165.WPD 26

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