Aluminum alkyls and linear 1-olefins from internal olefins

Details Aluminum alkyls and linear 1-olefins from internal olefins Aluminum alkyls and linear 1-olefins from internal olefins

C - Chemistry, Metallurgy

07

C

C07C 5/25 (2006.01) C07C 1/32 (2006.01) C07C 11/02 (2006.01) C07F 5/06 (2006.01)

Patent

CA 2062553

Linear 1-olefins are prepared from internal olefins by (i) reacting them in the presence of an isomerization catalyst and a tri-lower alkyl aluminum so as to cause the internal olefin to isomerize to 1-olefins which displace the lower alkyl groups to form a trialkyl aluminum compound in which at least one of the alkyl groups is a linear alkyl derived from the 1-olefin, and, thereafter, (ii) reacting the trialkyl aluminum compound with a 1-olefin so as to displace the linear alkyl from the trialkyl aluminum compound, thereby forming a linear 1-olefin product which is substantially free of internal olefins.

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