Multi-functional unsaturated polyester polyols

C - Chemistry – Metallurgy – 08 – G

Patent

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Details

C08G 63/08 (2006.01) C08G 18/48 (2006.01) C09D 129/02 (2006.01) C09D 167/06 (2006.01) C09D 167/07 (2006.01)

Patent

CA 2417458

Novel multifunctional unsaturated polyester polyols, UV-curable top coat formulations including these polyols, and a one-step process for preparing these polyols, are disclosed. Surface coverings and surface covering components including these top coat formulations are also disclosed. The polyols are generally formed by the ring opening polymerization of a lactone with a compound of the formula (R1)aR(OH)b, where a + b > 2. R1 is a double bond-containing moiety such as allyl, vinyl, vinylidene, vinyl ether, acrylate, and the like. R is generally an alkyl, aryl, aralkyl, alkaryl, ether or ester group, including substituted versions thereof. R can be a polymer, including polymers with a plurality of functional groups. Examples of lactone groups which can be used include caprolactone, lactide and glycolide. The polyols can be used in 100% solids, solvent and water based radiation cured coatings, thermal cured coatings, dual cure (thermal with UV/e- beam, or UV/e-beam with thermal curing) coatings, and other types of coatings. These new resins enhance coating performance due to their multi-functional groups in the polymer chain.

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