C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
C07C 51/353 (2006.01) C07C 53/126 (2006.01) C07C 57/02 (2006.01) C07C 67/333 (2006.01) C07C 69/24 (2006.01)
Patent
CA 2398578
A process for the branching of saturated and/or unsaturated fatty acids and/or alkyl esters thereof comprises subjecting the fatty acids and/or alkyl esters to a skeletal isomerization reaction using a catalyst comprising a crystalline porous structure having incorporated therein a metal to form metal sites on said catalyst and isolating branched fatty acids, alkyl esters thereof, or mixtures thereof, from a reaction mixture obtained by said skeletal isomerization reaction. The catalyst used in the isomerization reaction is preferably a zeolite catalyst containing metal sites of a Group VIII metal. The process produces a mixture of fatty acids and/or alkyl esters that contain significant quantities of branched molecules.
L'invention concerne un procédé de ramification d'acides gras saturés et/ou insaturés et/ou d'alkyl esters de ceux-ci, qui consiste à soumettre les acides gras et/ou les alkyl esters à une réaction d'isomérisation de squelette, au moyen d'un catalyseur présentant une structure cristalline poreuse dans laquelle est incorporé un métal destiné à former des sites métalliques sur ledit catalyseur, et à isoler les acides gras ramifiés, les alkyl esters de ceux-ci ou les mélanges de ceux-ci, d'un mélange réactionnel obtenu par ladite réaction d'isomérisation de squelette. Le catalyseur utilisé dans la réaction d'isomérisation est, de préférence, un catalyseur au zéolite contenant des sites métalliques d'un métal de Groupe VIII. Ledit procédé permet la production d'un mélange d'acides gras et/ou d'alkyl esters contenant des quantités importantes de molécules ramifiées.
Connor Daniel Stedman
Kenneally Corey James
Kirby Eades Gale Baker
The Procter & Gamble Company
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