Silicone monomers and oligomers having a carboxyl functional...

C - Chemistry – Metallurgy – 07 – F

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C07F 7/02 (2006.01) C07F 7/08 (2006.01) C07F 7/10 (2006.01) C07F 7/18 (2006.01) C08G 77/04 (2006.01) C08G 77/388 (2006.01)

Patent

CA 2272557

There is provided organosilane compounds containing one or more carboxyl acid group(s) that may be represented by general formula (I) wherein: R which can be the same or different, are hydrogen, and monovalent hydrocarbon radicals and substituted hydrocarbon radicals; R1 which can be the same or different can be substituted or unsubstituted alkyl, substituted or unsubstituted aryl, alkenyl, alkynyl or -R2 -Bnl -Fn -R3; x can be zero to 3; R2 is linear or branched alkylene of 1-12 carbon atoms; B is -NR6, sulfur or oxygen; R6 is hydrogen or lower alkyl (C1-6); n1 is zero or 1; F is linear or branched alkylene of 1-10 carbon atoms; n is zero or 1, with the proviso that if n1 is 1, n is 1 and if n1 is 0, n is 0; R3 is (II); R5 is hydrogen, lower alkyl (C1- 6) or alkali metal.

Composés d'organosilane contenant un ou plusieurs groupe(s) d'acide carboxylique, pouvant être représentés par la formule générale (I) dans laquelle les radicaux R, qui peuvent être identiques ou différents, sont l'hydrogène et des radicaux hydrocarbures monovalents et substitués; R?1¿ qui peut être identique ou différent peut représenter un alkyle substitué ou non substitué, un aryle substitué ou non substitué, aryle, alcényle, alcynyle substitués ou non substitués ou -R?2¿ -B¿n1? -F¿n? -R?3¿; x est compris entre zéro et 3; R?2¿ est un alkylène linéaire ou ramifié comportant 1 à 12 atomes de carbone; B est -NR?6¿, du soufre ou de l'oxygène; R?6¿ est de l'hydrogène ou un alkyle inférieur en C¿1-6?; n?1¿ représente zéro ou 1; F est un alkylène linéaire ou ramifié comprenant de 1 à 10 atomes de carbone; n est zéro ou 1 à condition que si n?1¿ est 1, n représente 1 et si n?1¿ est 0, n représente 0; R?3¿ est (II); R?5¿ est de l'hydrogène un alkyle inférieur en C¿1-6? ou un métal alcalin.

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