Process for preparing (1h-tetrazol-5-yl)tetrazolo [1,5-a]...

C - Chemistry – Metallurgy – 07 – D

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C07D 471/04 (2006.01) C07D 471/14 (2006.01) C07D 491/147 (2006.01) C07D 491/22 (2006.01)

Patent

CA 2184694

A process according to reaction scheme (I), wherein n is 0, 1 or 2, R is C1-4 alkyl, C1-4 alkoxy, halogen, methylmercapto, methylsulfonyl, or two R's can be combined as methylenedioxy; B is either nitrogen or CH; and X is a suitable leaving group; M is a lower alkali metal cation; with the proviso that, when R is methylmercapto or methylsulfonyl, then n must be 1.

L'invention concerne un procédé utilisant le schéma réactionnel I. Dans les formules, n est égal à 0, 1 ou 2, R est un C¿1-4?alkyle, un C¿1-4?alcoxy, un halogène, un méthylmercapto, un méthylsulfonyle ou deux R peuvent être joints pour former un groupe méthylènedioxy; B est l'azote ou un CH; et X est un groupe libéré approprié; M est un cation de métal alcalin à bas poids atomique. Une condition à satisfaire est que, lorsque R est un méthylmercapto ou un méthylsulfonyle, n doit être égal à 1.

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