Preparation of saccharincarboxylic acids and -carboxylic...

C - Chemistry – Metallurgy – 07 – D

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C07D 275/06 (2006.01) A01N 43/80 (2006.01)

Patent

CA 2197120

The invention pertains to novel herbicidally effective saccharin carboxylic acids or carboxylic acid esters of formula (Ia), in which the substituents are as follows: L, M are hydrogen, C1-C4 alkyl, C1-C4 alkoxy C1-C4 alkylthio, chlorine, cyano, methyl sulfonyl, nitro or trifluoromethyl; Z is hydrogen, C1- C4 alkyl, C3-C8 cycloalkyl, benzyl or phenyl, where the penyl rings can in each case be substituted by C1-C4 alkyl, and R is H, C1-C6 alkyl, with the proviso that if L and M are hydrogen, Z is not methyl, phenyl hydrogen or an alkali metal cation or silver cation, and also excepting 5-carboxy-7-methyl saccharin and 5-carboxy-4-chlorosaccharin.

L'invention concerne de nouveaux acides carboxyliques et esters d'acide carboxylique de saccharine présentant des propriétés herbicides, de formule (Ia) où L, M représentent hydrogène, alkyle comportant un à quatre atomes de carbone, alcoxy comportant un à quatre atomes de carbone, alkylthio comportant un à quatre atomes de carbone, chlore, cyano, méthylsulfonyle, nitro ou trifluorométhyle; Z représente hydrogène, alkyle comportant un à quatre atomes de carbone, cycloalkyle comportant trois à huit atomes de carbone, benzyle ou phényle, les noyaux phényle pouvant être substitués chacun par alkyle comportant un à quatre atomes de carbone; R représente hydrogène, alkyle comportant un à six atomes de carbone, à condition que Z ne représente pas méthyle, phényle, hydrogène ou un cation de métal alcalin ou d'argent, si L et M représentent hydrogène, et ne représente pas 5-carboxy-7-méthylsaccharine ni 5-carboxy-4-chlorosaccharine.

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