Isoparaffin-olefin alkylation with mcm microporous material...

Details Isoparaffin-olefin alkylation with mcm microporous material... Isoparaffin-olefin alkylation with mcm microporous material...

C - Chemistry, Metallurgy

07

C

C07C 9/16 (2006.01) C07C 2/58 (2006.01)

Patent

CA 2141190

A process for alkylating an olefin with an isoparaffin comprising contacting an olefin-containing feed with an isoparaffin- containing feed in the presence of crystalline microporous materials such as MCM-22, MCM-36, and MCM-49, under alkylating conditions, including temperatures at least equal to the critical temperature of the principal components, primarily isoparaffin, and at pressures at least equal to the critical pressure of the principal component of the feed, primarily the isoparaffin. Specific examples include the alkylation of an isobutane-n-butene feed mixture under the supercritical conditions of the principal compo- nent of the feed, namely isobutane, as isobutane is used in large excess to promote the selective formation of the alkylate.

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