Process for preparing metal-free fatty peroxyacid precursors...

C - Chemistry – Metallurgy – 07 – C

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260/487.2, 260/5

C07C 235/74 (2006.01) C07C 231/02 (2006.01)

Patent

CA 2036996

PROCESS FOR PREPARING METAL-FREE FATTY PERACID PRECURSORS HAVING AMIDE MOITETIES IN THE FATTY CHAIN ABSTRACT A process for preparing metal-free precursors for amide containing organic peracids is disclosed wherein a polycarboxylic acid is esterfied with a low molecular weight alkyl alcohol followed by formation of an amide by reacting the ester with an amine to provide a monoamido carboxylic acid ester. The ester is recovered from the reaction mixture by a distillation procedure under high temperature and reduced pressure. The esters are converted to acids highly desireable as precursers for peracids useful as bleaches in laundry detergents.

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