Synthesis of 6-aryl-6-alkyl fulvenes, 6-aryl-6-alkenyl...

C - Chemistry – Metallurgy – 07 – F

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Details

C07F 17/00 (2006.01) C07C 2/86 (2006.01) C07C 13/15 (2006.01)

Patent

CA 2570152

The present invention provides a method of making fulvenes, particularly 6- aryl-6-alkylfulvenes, 6-aryl-6-alkenylfulvenes, and related compounds, by combining alkyl- or alkenyl-arylketones with magnesium cyclopentadienyl reagents in nonprotic, including ethereal, solvents. The use of these compounds in preparing bis(cyclopentadienyl)methanes and related compounds, and ansa-metallocenes, is disclosed.

La présente invention concerne un procédé de production de fulvènes, en particulier de 6-aryl-6-alkylfulvènes, de 6-aryl-6-alcénylfulvènes et de composés associés, lequel procédé consiste à combiner des alkyl- ou alcényl-arylcétones et des réactifs cyclopentadiényle-magnésium dans des solvants non protiques, y compris des solvants éthérés. Cette invention porte également sur l'utilisation de ces composés pour préparer des bis(cyclopentadiényl)méthanes et des composés associés, ainsi que des ansa-métallocènes.

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