Process for the production of styrene

C - Chemistry – Metallurgy – 07 – C

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C07C 15/46 (2006.01) B01J 23/18 (2006.01) C07C 5/48 (2006.01)

Patent

CA 2158342

4-Vinylcyclohexene is converted to styrene in the presence of a catalyst comprising tin, antimony, and oxygen. The feed stream to be contacted with the catalyst comprises water, 4-vinylcyclohexene, and oxygen. A ratio of water to 4-vinylcyclohexene above 12:1, preferably above 14:1, significantly increases the half-life of the catalyst. The catalyst is prepared by coprecipitating a tin chloride and an antimony chloride followed by calcination of the precipitate at a temperature in the range from 850 °C to 1000 °C.

Le tétravinylcyclohexane se convertit en styrène en présence d'un catalyseur composé d'étain, d'antimoine et d'oxygène. Le flux d'alimentation à mettre en contact avec le catalyseur est un mélange d'eau, de tétravinylcyclohexane et d'oxygène. Un rapport eau/tétravinylcyclohexane supérieur à 12/1, et de préférence égal à 14/1, augmente de façon remarquable la demi-vie du catalyseur. Le catalyseur est préparé par coprécipitation de chlorure d'étain et de chlorure d'antimoine, le précipité étant soumis à une calcination à une température située entre 850 DEG C et 1000 DEG C.

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