Wastewater ammonium extraction and electrolytic conversion...

C - Chemistry – Metallurgy – 02 – F

Patent

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C02F 9/06 (2006.01) C02F 1/26 (2006.01) C02F 1/44 (2006.01) C02F 1/461 (2006.01) C02F 1/58 (2006.01) C02F 1/66 (2006.01) C02F 9/02 (2006.01) C25B 1/00 (2006.01) C25B 9/00 (2006.01) C25B 15/08 (2006.01)

Patent

CA 2631080

A new system is disclosed for extracting ammonia from a wastewater stream, and for transferring the ammonia into the secondary water circuit, where the dissolved ammonium is electrolysed and transformed into gaseous nitrogen. The new system makes use of a membrane of gas--permeable hydrophobic material. The wastewater is raised to pH of 11, and 50°C, to make the transfer of ammonia through the membrane more efficient. Also disclosed is a process-control system for the ammonium disposal system, in which pH sensors are used to control operation. Instruments for measuring ammonia-concentration directly are expensive, whereas pH- sensors are simple, reliable, and responsive. Disclosed are procedures for establishing the relationships between pH and the progress of the ammonium disposal treatment.

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