Preparation of metallocenes carrying a cyclopentadiene...

C - Chemistry – Metallurgy – 07 – F

Patent

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C07F 17/00 (2006.01)

Patent

CA 2394308

The invention provides a method for the preparation of a metallocene halide salt having at least one cyclopentadiene group substituted by a basic group, the method comprising reacting together a metal halide with a cyclopentadiene substituted by a basic group. In a preferred embodiment, the substituted cyclopentadiene is substituted with an amino group and the metal halide titanium tetrachloride. The invention provides a single step process for the preparation of metallocene derivatives which are useful in the formulation of medicaments and as polymerisation catalyst precursors.

L'invention concerne un procédé de préparation d'un halogénure de métallocène, comportant au moins un groupe cyclopentadiène substitué par un groupe basique, qui consiste à faire réagir ensemble un halogénure métallique et un cyclopentadiène substitué par un groupe basique. Dans une réalisation préférée, le cyclopentadiène est substitué par un groupe amino et l'halogénure métallique est du tétrachlorure de titane. L'invention concerne un procédé à étape unique pour la préparation de dérivés métallocènes qui sont utiles dans la formulation de médicaments et comme précurseurs de catalyseurs de polymérisation.

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