Carboxamides as fungicides in agriculture

C - Chemistry – Metallurgy – 07 – D

Patent

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Details

C07D 207/34 (2006.01) A01N 43/00 (2006.01) C07D 231/14 (2006.01) C07D 277/56 (2006.01)

Patent

CA 2433819

The invention concerns novel carboxamides of formula (I) wherein A is (A1), (A2), (A3), (A4), (A5); Q is (Q1), (Q2), (Q3), (Q4), (Q5), (Q6); R1 is CH2 R2, CH2CH=CHR2, CH=C=CHR2 or COR3; R2 is hydrogen, C1-C6alkyl, C1-C6haloalkyl, C2- C6alkenyl, C2-C6alkynyl, C3-C7cycloalkyl, COOC1-C4alkyl, COOC3-C6alkenyl, COOC3-C6alkynyl or CN; R3 is C1-C6alkyl, C1-C6alkyl substituted by halogen, C1- C6alkoxy or C1-C6haloalkoxy; or is C1-C6alkylthio, C1-C6haloalkylthio, C1- C6alkoxy, C1-C6haloalkoxy; C3-C6alkenyloxy or C3-C6haloalkenyloxy; C3- C6haloalkenyloxy; C3-C6alkynyloxy or C3-C6haloalkynyloxy; R4 is methyl, CF2Cl, CF3, CF2H, CFH2, Cl or Br; R5 is methyl, CF3, CH2OCH3 or CH2OCF3; R6 is hydrogen, fluoro, CF3 or methyl; R7 is hydrogen, methyl or halogen; and Z is phenyl, halophenyl, C5-C7cycloalkyl, C5-C7cycloalkyl substituted by C1- C3alkyl, C1-C3haloalkyl or halogen, or a group of the form -CHR8-CH2-CHR9R10 wherein R8, R9 and R10 are independently of each other C1-C3alkyl. The novel compounds have plant-protective properties and are suitable for protecting plants against infestation by phytopathogenic microorganisms, in particular fungi.

La présente invention concerne de nouveaux carboxamides représentés par la formule (I), selon laquelle A représente (A1), (A2), (A3), (A4) et (A5); Q représente (Q1), (Q2), (Q3), (Q4), (Q5) et (Q6) ; R¿1? représente CH¿2? R¿2?, CH¿2?CH=CHR¿2?, CH=C=CHR¿2 ?ou COR¿3? ; R¿2? représente hydrogène, alkyle C¿1?-C¿6?, haloalkyle C¿1?-C¿6?, alcényle C¿2?-C¿6?, alkynyle C¿2?-C¿6?, cycloalkyle C¿3?-C¿7?, alkyle COOC¿1?-C¿4?, alcényle COOC¿3?-C¿6?, alkynyle COOC¿3?-C¿6? ou CN; R¿3? représente alkyle C¿1?-C¿6?, alkyle C¿1?-C¿6? substitué par un halogène, alcoxy C¿1?-C¿6? ou haloalcoxy C¿1?-C¿6 ?; ou représente alkylthio C¿1?-C¿6?, haloalkylthio C¿1?-C¿6?, alcoxy C¿1?-C¿6?, haloalcoxy C¿1?-C¿6 ?; alcényloxy C¿3?-C¿6? ou haloalcényloxy C¿3?-C¿6?; haloalcényloxy C¿3?-C¿6?; alkynyloxy C¿3?-C¿6? ou haloalkynyloxy C¿3?-C¿6?; R¿4? représente méthyle, CF¿2?Cl, CF¿3?, CF¿2?H, CFH¿2?, Cl ou Br ; R¿5? représente méthyle, CF¿3?, CH¿2?OCH¿3? ou CH¿2?OCF¿3? ; R¿6? représente hydrogène, fluor, CF¿3? ou méthyle ; R¿7? représente hydrogène, méthyle ou halogène ; et Z représente phényle, halophényle, cycloalkyle C¿5?-C¿7?, cycloalkyle C¿5?-C¿7? substitué par un alkyle C¿1?-C¿3?, haloalkyle C¿1?-C¿3? ou halogène, ou un groupe de la forme -CHR¿8?-CH¿2?-CHR¿9?R¿10?, R¿8?, R¿9? et R¿10? représentant indépendamment les uns des autres alkyle C¿1?-C¿3?. Les nouveaux composés présentent des propriétés phytoprotectrices et peuvent protéger les végétaux contre des infestations de micro-organismes phytopathogènes, en particulier les champignons.

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