Process for the preparation of tertiary aminocarbonates and...

C - Chemistry – Metallurgy – 07 – C

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C07C 219/16 (2006.01) C07C 68/06 (2006.01) C07C 69/96 (2006.01) C07C 209/68 (2006.01) C07C 211/10 (2006.01) C07C 213/00 (2006.01) C07C 213/06 (2006.01) C07C 217/04 (2006.01) C07D 295/03 (2006.01) C07D 295/088 (2006.01)

Patent

CA 2222062

The invention relates to processes for producing di-(tertiary aminoalkyl) carbonate including the step of reacting a tertiary alkanolamine with methyl alkyl carbonate in the presence of a transesterification catalyst to form tertiary aminoalkyl alkyl carbonate, wherein some of the tertiary alkanolamine reacts with the tertiary aminoalkyl alkyl carbonate to form di-(tertiary aminoalkyl) carbonate. The invention also relates to processes for producing di-(tertiary aminoalkyl) carbonate including the steps of (i) reacting dimethyl carbonate with an alcohol in the presence of a transesterification catalyst to form a methyl alkyl carbonate, and (ii) reacting a tertiary alkanolamine with the methyl alkyl carbonate formed in step (i) in the presence of a transesterification catalyst to form tertiary aminoalkylalkyl carbonate, wherein some of the tertiary alkanolamine reacts with the tertiary aminoalkyl alkyl carbonate to form di-(tertiary aminoalkyl) carbonate.

L'invention porte sur des procédés d'élaboration d'un carbonate de di-(aminoalkyle tertiaire) consistant à faire réagir une alcanolamine tertiaire avec un carbonate de méthylalkyle en présence d'un catalyseur de transestérification pour constituer un carbonate d'aminoalkylalkyle tertiaire, une partie de l'alcanolamine tertiaire réagissant avec le carbonate d'aminoalkylalkyle tertiaire pour former un carbonate de di-(aminoalkyle tertiaire). L'invention porte également sur des procédés d'élaboration d'un carbonate de di-(aminoalkyle tertiaire) consistant, i), à faire réagir du carbonate de diméthyl avec un alcool en présence d'un catalyseur de transestérification pour constituer un carbonate de méthylalkyle et, ii), à faire réagir l'alcanolamine tertiaire avec le carbonate de méthylalkyle obtenu au cours de l'étape (i) en présence d'un catalyseur de transestérification pour former un carbonate d'aminoalkylalkyl tertiaire, une partie de l'alcanolamine tertiaire réagissant avec le carbonate d'aminoalkylalkyl tertiaire pour former un carbonate de di-(aminoalkyle tertiaire).

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