Solid state cyanocobaltate complexes

C - Chemistry – Metallurgy – 07 – F

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C07F 15/06 (2006.01) B01J 20/02 (2006.01) B01J 20/04 (2006.01) B01J 20/22 (2006.01) C01C 3/11 (2006.01)

Patent

CA 2083209

PATENT 173PUSO4670 ABSTRACT High capacity solid state cyanocobaltate complexes represented by the chemical formula: Li3[Co(CN)5]-1.42 DMF-0.48 DMAC where DMF is N,N-dimethylformamide and DMAC is N,N-dimethylacetamide are capable of chemically binding oxygen to form novel oxygen adducts, thereby selectively removing oxygen from an oxygen-containing fluid stream. The bound oxygen may be recovered from the complexes by increasing the temperature or by reducing the partial pressure of O2 above the adduct.

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