Block copolymers of polysiloxanes and copolymers of...

C - Chemistry – Metallurgy – 08 – G

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C08G 81/00 (2006.01) B32B 25/10 (2006.01) B32B 27/08 (2006.01) C08G 77/442 (2006.01) C08L 53/02 (2006.01) C08L 83/10 (2006.01)

Patent

CA 2072671

FS-9008061 ABSTRACT Title: BLOCK COPOLYMERS OF POLYSILOXANES AND COPOLYMERS OF CONJUGATED DIENES AND AROMATIC VINYL COM- POUNDS, AND MULTILAYER STRUCTURES CONTAINING SAME Block copolymers are described which comprise alternating blocks of (A) a polysiloxane; and (B) a copolymer of a 1,3-conjugated diene and a monovinyl aromatic compound. The block copolymers can be prepared by reacting a polysiloxane with a dilithiated copolymer of a conjugated diene and a monovinyl aromatic compound and thereafter neutralizing the reaction product with a protonic acid or a polyfunctional alkyl silane or silicon tetrachloride. Cured elastomer compositions exhibiting surface release characteristics are obtained by curing a mixture comprising the above-described block copolymer in the presence of a curing system comprising a peroxide and sulfur. Multilayer elastomer structures useful in manufacturing articles from elastomeric materialsalso are described wherein at least a portion of an outer layer of the multilayer elastomer structure has release characteristics and comprises the cured block copolymers of the present invention.

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