Microcellular polyurethane elastomer and process for...

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 18/42 (2006.01) C08G 18/10 (2006.01) C08G 18/12 (2006.01) C08G 18/48 (2006.01) C08G 18/76 (2006.01) C08J 9/04 (2006.01) C08L 75/06 (2006.01) C08L 75/08 (2006.01)

Patent

CA 2143389

A microcellular polyurethane elastomer obtained by mixing an NCO-terminated prepolymer, an OH-terminated prepolymer and a foaming component with stirring to cause foaming and curing is disclosed, in which the NCO-terminated prepolymer is (A) a prepolymer obtained by reacting a polyester polyol (a) having a number average molecular weight of 1,000 to 3,000 and diphenylmethane-4,4'-diisocyanate (MDI) or (B) a partially crosslinked prepolymer obtained by further reacting the reaction product of polyester polyol (a) and MDI with a low-molecular weight polyol, the OH-terminated prepolymer is (A) a prepolymer obtained by reacting polyester polyol (a) with a polyisocyanate or (B) a prepolymer obtained by reacting polyester polyol (b) and/or a polyether polyol both having a number average molecular weight of 500 to 3,000 with a polyisocyanate, and the foaming component contains water as a main blowing agent, which elastomer exhibits improved resistance to fatigue failure and permanent set in a fatigue test while retaining advantages of the use of MDI.

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