Stable aqueous dispersions of hydrophilic phenolic resins...

C - Chemistry – Metallurgy – 08 – L

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Details

C08L 61/14 (2006.01) C08J 3/03 (2006.01) C08J 3/07 (2006.01) C08L 61/06 (2006.01)

Patent

CA 2604734

Storage stable aqueous dispersions of a heat-reactive hydrophilic phenolic resin (e.g., phenol/formaldehyde) are disclosed. The dispersions comprise a base resin that is the reaction product of an aromatic alcohol and an aldehyde, and an etherified resin component selected from the group consisting of an etherified phenol/aldehyde resin, an etherified cresol/aldehyde resin, and mixtures thereof. The dispersions further comprise a protective colloid (e.g., polyvinyl alcohol). The addition of the etherified resin component in an amount of at least about 20% by weight of the base resin provides storage stability, but does not adversely affect the desirable physical and chemical characteristics (e.g., chemical resistance) of end products made from such dispersions. Moreover, the dispersions of the present invention can avoid the use of etherified resin components derived from bisphenol-A and/or xylenols, which present heath concerns in food coating applications.

L'invention porte sur des dispersions aqueuses stables à l'entreposage de résine phénolique hydrophile thermoréactive (par exemple de phénol/formaldéhyde) comportant une résine de base, produit de la réaction d'un alcool aromatique et d'une aldéhyde, et une résine éthérifiée choisie parmi une résine éthérifiée de phénol/aldéhyde, une résine éthérifiée de crésol/aldéhyde, et leurs mélanges. Ces dispersions comportent en outre un colloïde protecteur (par exemple de l'alcool de polyvinyle). L'adjonction de résine éthérifiée à raison d'environ 20 % en poids de la résine de base confère la stabilité à l'entreposage, sans affecter les caractéristiques physiques et chimiques (par exemple la résistance chimique) des produits finaux faits de telles dispersions. De plus lesdites dispersions permettent d'éviter l'utilisation de résines éthérifiées dérivant du bisphénol-A et/ou de xylénols, qui posent des problèmes en matière d'applications alimentaires.

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