Process for the preparation of tertiary alcohols containing...

C - Chemistry – Metallurgy – 07 – C

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C07C 29/62 (2006.01) C07C 29/44 (2006.01) C07C 31/38 (2006.01)

Patent

CA 2049771

- 1 - HOE 90/F 910 Abstract of the disclosure Process for the preparation of tertiary alcohols containing fluorine In the process described tertiary fluoroalcohols of the following formula Image in which Rf is a perfluoroalkyl radical having 4 to 20 carbon atoms, R1 is CH3 and R2 is CH3 or C2H5, are prepared by reacting perfluoroalkylethylenes of the formula Rf-CH=CH2 in which Rf has the meaning indicated, with excess isopropanol or excess sec.-butanol in the presence of free-radical initiators.

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