Biosynthetic pathway and genes required for tropodithietic...

C - Chemistry – Metallurgy – 12 – N

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C12N 15/52 (2006.01) A61K 31/385 (2006.01) A61P 31/04 (2006.01) C07C 61/26 (2006.01) C07C 317/46 (2006.01) C07D 339/00 (2006.01) C12N 9/00 (2006.01) C12N 15/63 (2006.01) C12N 15/74 (2006.01) C12P 17/00 (2006.01) C12N 15/31 (2006.01)

Patent

CA 2670626

The symbiotic association between the roseobacter Silicibacter sp. TM1040 and the dinoflagellate Pfiesteria piscicida involves bacterial chemotaxis to dinoflagellate-produced dimethylsulfoniopropionate (DMSP), DMSP demethylation, and ultimately a biofilm on the surface of the host. Biofilm formation is coincident with the production of an antibiotic and a yellow-brown pigment. The antibiotic is a sulfur-containing compound, tropodithietic acid (TDA). Using random transposon insertion mutagenesis, 12 genes were identified as critical for TDA biosynthesis by the bacteria, and mutation in any one of these results in loss of antibiotic activity (Tda ) and pigment production. A biosynthetic and regulatory pathway for TDA biosynthesis in roseobacters is described.

L'association symbiotique entre le roséobacter Silicibacter sp. TM1040 et le dinoflagellé Pfiesteria piscicida entraîne une chimiotaxie bactérienne impliquant le diméthylsulfoniopropionate (DMSP) produit par le dinoflagellé, une méthylation de DMSP et, enfin, la formation d'un film biologique sur la surface du récepteur. La formation de ce film biologique coïncide avec la production d'un antibiotique et d'un pigment jaune-brun. Cet antibiotique est un composé contenant du soufre, acide tropodithiétique (TDA). La mutagénèse sélective par insertion de transposons a permis d'identifier 12 gènes jouant un rôle important dans la biosynthèse de TDA par la bactérie et toute mutation dans ces gènes a pour effet une perte de l'activité antibiotique (Tda) et de la production de pigment. L'invention concerne une voie de biosynthèse et de régulation pour la biosynthèse de TDA dans des roséobacters.

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