Acrylic-halogenated polyolefin copolymer adhesion promoters

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 293/00 (2006.01) C08F 4/72 (2006.01) C08F 8/30 (2006.01) C08F 210/00 (2006.01) C08F 220/02 (2006.01) C08J 7/04 (2006.01)

Patent

CA 2436568

The present invention is directed to a method for producing a copolymer and a copolymer product of the method. The copolymer is prepared by a controlled radical polymerization process, typically an atom transfer radical polymerization process, in which polymerizable alkene monomers are polymerized in the presence of a halogenated polyolefin macroinitiator. The copolymer product of this process is useful in a film-forming composition that adheres strongly to polyolefinic substrates and to which non-polyolefinic film-forming compositions strongly adhere. The copolymer can be applied to a substrate in an adhesion-promoting layer or can be incorporated into a film-forming composition, such as a primer, that contains additional resinous compounds.

L'invention concerne un procédé servant à préparer un copolymère, ainsi qu'un copolymère obtenu au moyen de ce procédé. On prépare ce copolymère par polymérisation radicalaire contrôlée, plus particulièrement, polymérisation radicalaire à transfert atomique, ce qui consiste à polymériser des monomères d'alcène polymérisable en présence d'un macro-initiateur de polyoléfine halogénée. Le copolymère obtenu au moyen de ce procédé est utile dans une composition de formation pelliculaire adhérant fermement à des substrats polyoléfiniques auxquels des compositions de formation pelliculaire non-polyoléfiniques peuvent également adhérer fermement. On peut appliquer ce copolymère à un substrat sous forme de couche favorisant l'adhérence ou on peut l'incorporer en tant qu'amorce, dans une composition de formation pelliculaire contenant des composés résineux additionnels.

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