Herbicidal 12-substituted...

C - Chemistry – Metallurgy – 07 – D

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260/351.1, 260/5

C07D 321/12 (2006.01) A01N 43/24 (2006.01) C07C 43/20 (2006.01) C07C 255/54 (2006.01) C07C 323/20 (2006.01)

Patent

CA 2018986

ABSTRACT Dibenzo[d,g][1,3]dioxocin-6-carboxylic acids substituted by methyl or ethyl or a moiety -CH2CH2- at the 12-position and optionally substituted at other positions, such as methyl 4'-chlorospiro(cyclopropane- -1,12'(12'H)-dibenzo[d,g][l,3]dioxocin)-6'-carboxylic acid, and their agriculturally acceptable esters, amides, and salts are useful for the control of undesirable vegetation. The 1,1-diarylcyclopropane intermediates required for the spirocyclopropane compounds can be prepared from appropriately substituted 1,1-diarylethene procursors by reaction with phenylthiomethyl lithium reagent.

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