Method for voltammetric electrochemical analysis and...

G - Physics – 01 – N

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G01N 27/48 (2006.01)

Patent

CA 2608080

The invention concerns a method for voltametric electrochemical analysis of a liquid solution, for detecting and/or assaying in said solution at least one chemical species. The invention is characterized in that the method includes the following steps: contacting a sample of said solution with a single analyzing support (10) having at least two working electrodes (12) each belonging to a separate electrochemical analysis cell, each analysis cell further including a counter-electrode (13) and a reference electrode; performing a single and different measurement of said sample in each of said analysis cells, by applying an independent and different potential to each of the working electrodes (12); producing at least one voltamogram of said sample, based on said measurements; deducing from said voltamogram data concerning the detection and/or assay of said at least one chemical species in said sample.

L'invention concerne un procédé d'analyse électrochimique par voltamétrie d'une solution liquide, permettant la détection et/ou le dosage dans ladite solution d'au moins une espèce chimique. Selon l'invention, le procédé comprend les étapes consistant à : - mettre en contact un échantillon de ladite solution avec un support d'analyse (10) unique présentant au moins deux électrodes de travail (12) appartenant chacune à une cellule d'analyse électrochimique dist incte, chaque cellule d'analyse comprenant en outre une contre- électrode (13) et une électrode de référence ; - effectuer une mesure unique et différente dudit échantillon dans chacune desdites cellules d'analyse, par application d'un potentiel indépendant et différent à chacune desdites électrodes de travail (12) ; - établir au moins un voltamogramme dudit échantillon, à partir desdites mesures ; - déduire dudit voltamogramme des informations relatives à la détection et/ou au dosage de ladite au moins une espèce chimique dans ledit échantillon.

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