Inhibitors of cancer cell, t-cell and keratinocyte...

C - Chemistry – Metallurgy – 07 – K

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C07K 5/04 (2006.01) A61K 38/04 (2006.01) C07D 233/00 (2006.01) C07K 5/06 (2006.01) C07K 5/08 (2006.01) C07K 5/10 (2006.01)

Patent

CA 2618750

The invention relates to compounds of the general formula (I) and salts and physiologically functional derivatives thereof, wherein Y is -NRaRb, - NRcC=ONRaRb' -NRcC=SNRaRb, -NRcC=NRdNaRb, heterocycle, - C=ONRaRb, heterocycle, or aryl; n is O to 8; m is 0, or 1 ; r is 0 to 3; t is O to 3; X is O or N; Z is CH2, C=O, C=S or a single bond; Z1 is CO-R2, CS-R2, (CH2)t-R2 or the side-chain of a naturally occuring amino acid; , Z2 is CO-R2 , CS-R2 or (CH2)t-R3 or the side-chain of a naturally occuring amino acid; Z3 is CO-R2, CS-R2 or (CH2)t-R4 or the side-chain of a naturally occuring amino acid; Z4 is H, alkyl, alkoxy, or cycloalkyl; R1, R2, R3, and R4 are independently from each other H, OH, SH, NH2, CN, NO2, alkyl, cycloalkyl, heterocycloalkyl, haloalkyl, alkylthio, haloalkyloxy, hydroxyalkyl, hydroxyalkylarnino, alkylamino, alkylaryl, alkylsulfinyl, alkylsulfonyl, alkylthioalkyl, alkylsulfinylalkyl, alkylsulfonylalkyl, alkoxyalkyl, alkoxy, aryloxy, heteroaryl, aryl, or halogen.

La présente invention concerne des composés représentés par la formule générale (I) et certains de leurs sels et dérivés physiologiquement fonctionnels. Dans cette formule Y est -NRaRb, -NRcC=ONRaRb, -NRcC=SNRaRb, -NRcC=NRdNaRb,, -C=ONRaRb, hétérocycle, ou aryle; n vaut 0 à 8; m vaut 0 ou 1; r vaut 0 à 3; t vaut 0 à 3; X est O ou N; Z est CH2, C=O, C=S ou une liaison simple; Z1 est CO-R2, CS-R2, (CH2)t-R2 ou la chaîne latérale d'un acide aminé naturel; Z2 est CO-R2,CS-R2 ou (CH2)t-R3 or the side-chain of a naturally occuring amino acid; Z3 is CO-R2, CS-R2 or (CH2)t-R4 ou la chaîne latérale d'un acide aminé naturel; Z4 est H, alkyle, alcoxy, ou cycloalkyle; R1, R2, R3, et R4 sont indépendamment les uns des autres H, OH, SH, NH2, CN, NO2, alkyle, cycloalkyle, hétérocycloalkyle, haloalkyle, alkylthio, haloalkyloxy, hydroxyalkyle, hydroxyalkylamino, alkylamino, alkylaryle, alkylsulfinyle, alkylsulfonyle, alkylthioalkyle, alkylsulfinylalkyle, alkylsulfonylalkyle, alcoxyalkyle, alcoxy, aryloxy, hétéroaryle, aryle ou halogène.

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