Method for preparing disubstituted monochlorotriazines

C - Chemistry – Metallurgy – 07 – D

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C07D 405/12 (2006.01) C07D 251/26 (2006.01) C07F 9/547 (2006.01) C07F 9/6521 (2006.01) C08G 65/48 (2006.01)

Patent

CA 2102487

METHOD FOR PREPARING DISUBSTITUTED MONOCHLOROTRIAZINES Abstract Disubstituted monochlorotriazines such as 2- chloro-4-mesitoxy-6-glycidoxy-1,3,5-triazine are prepared in organic solution by first combining a monoorganoxy dichlorotriazine with an aqueous alkali metal hydroxide solution in a specific concentration and molar ratio, and adding to the mixture thus produced a hydroxyaliphatic or hydroxyaromatic compound, preferably glycidol, in the presence of at least one hydrophilic phase transfer catalyst such as tetra-n-butylammonium bromide. The reaction can be integrated with either or both of a prior step of dichlorotriazine preparation and a subsequent step of capping a hydroxy-terminated polymer, especially a polyphenylene ether.

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