Process of reaction injection molding using...

C - Chemistry – Metallurgy – 08 – G

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C08G 18/79 (2006.01) B29C 45/00 (2006.01)

Patent

CA 2128185

A PROCESS OF REACTION INJECTION MOLDING USING ALLOPHANATE-MODIFIED LIQUID METHYLENE DIPHENYL DIISOCYANATE ABSTRACT OF THE DISCLOSURE The present invention relates to a process for injecting a reaction mixture into a closed mold via a reaction injection molding (RIM) machine with the ratio of the components being such that the isocyanate index is about 80 to 120, said reaction mixture comprising: (i) an isocyanate reactive material, (ii) a chain extender, and (iii) a stable, liquid MDI prepolymer containing an allophanate-modified MDI having an isocyanate content of about 12 to 32.5% which is a reaction product of an aliphatic alcohol and an isomer composition of diphenylmethane diisocyanate comprising from 2 to 60% by weight 2,4'-diphenylmethane diisocyanate and less than 6% by weight of the 2,2'-diphenylmethane diisocyanate, and the rest being 4,4'-diphenylmethane diisocyanate.

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