Process for the preparation of disulfides from thiols

C - Chemistry – Metallurgy – 07 – C

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C07C 323/12 (2006.01) B01J 27/057 (2006.01) C07C 319/24 (2006.01) C07C 321/14 (2006.01)

Patent

CA 2072763

ABSTRACT OF THE DISCLOSURE Process for the preparation of disulfides from thiols The process oxidizes thiols to disulfides using elemental selenium as a catalyst. Elemental selenium complexes with the thiol to form the species RSSe which is rapidly oxidized by molecular oxygen to the disulfide RSSR.

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