Improved epoxide isomerization catalysts

Details Improved epoxide isomerization catalysts Improved epoxide isomerization catalysts

B - Operations, Transporting

01

J

B01J 27/18 (2006.01) C07C 29/56 (2006.01) C07C 33/03 (2006.01)

Patent

CA 2157129

Improved catalysts for isomerizing epoxides to allylic alcohols are disclosed. The catalysts contain lithium phosphate supported on high-purity silica. The use of high-purity silica as a support results in improved epoxide conversion and allylic alcohol selectivity, and reduced by-product generation. The invention includes a process for isomerizing epoxides using the catalysts. The process is well- suited to the manufacture of allyl alcohol from propylene oxide.

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