Process for preparing highly metal exchanged zeolite y

C - Chemistry – Metallurgy – 01 – B

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C01B 39/24 (2006.01) B01J 29/08 (2006.01)

Patent

CA 2145202

Polyvalent metal zeolite Y of extremely low alkali metal content is prepared by a process of potassium ion exchange followed by polyvalent metal ion exchange. Zeolite NaY is contacted with a potassium salt solution under conditions that provide a substantial substitution of potassium for sodium. The predominately potassium zeolite Y is contacted with a solution containing at least one polyvalent metal salt under conditions that provide exchange of the polyvalent metal for both sodium and potassium. The resulting polyvalent zeolite Y contains less than 05 % alkali metal calculated as Na2O.

Zéolite Y métallique polyvalente à teneur extrêmement faible en métaux alcalins qui est préparée par un processus d'échange d'ions de potassium suivi par un échange d'ions métalliques polyvalents. La zéolite NaY est mise en contact avec une solution de sel de potassium dans des conditions qui permettent la substitution pratiquement intégrale du sodium par le potassium. La zéolite Y à prédominance de potassium est mise en contact avec une solution contenant au moins un sel de métal polyvalent dans des conditions qui permettent le remplacement du sodium et du potassium par du métal polyvalent. La zéolite Y polyvalente qui en résulte contient moins de 0,5 % de métaux alcalins calculés sous forme de Na2O.

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