Process for the polymerization of olefins; polyolefins, and...

C - Chemistry – Metallurgy – 08 – F

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C08F 10/00 (2006.01) C08F 210/16 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01)

Patent

CA 2377259

A process for the polymerization of olefins is provided. The process involves contacting at least one olefin with at least one metallocene catalyst in the presence of a specified compound that results in the production of polymeric products having a narrower molecular weight distribution. Also provided is a process for narrowing the molecular weight distribution of a polyolefin comprising contacting an olefin, at least one metallocene catalyst and a compound specified herein. Further provided are polyolefins, and films and articles produced therefrom.

L'invention concerne un procédé polymérisation d'oléfines. Le procédé comporte la mise en contact d'au moins une oléfine avec au moins un catalyseur métallocène en présence d'un composé spécifié, qui permet de produire des produits polymères présentant une distribution des masses moléculaires plus étroite. L'invention concerne aussi un procédé visant à resserrer la distribution des masses moléculaires d'une polyoléfine, qui comporte la mise en contact d'une oléfine avec au moins un catalyseur métallocène et un composé spécifié. L'invention concerne en outre des polyoléfines, ainsi que des films et des articles produits à partir de celles-ci.

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