Mixed catalyst compositions for the production of polyolefins

C - Chemistry – Metallurgy – 08 – F

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C08F 10/00 (2006.01) C08F 4/651 (2006.01) C08F 110/06 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2485168

A solid, hydrocarbon insoluble catalyst composition comprising: A) a solid, particulated complex comprising moieties of at least magnesium, a Group 4 transition metal, and a halide; B) one or more .alpha.-amino-substituted- or .alpha.-imino- substituted- 2-alkylpyridine compounds; C) one or more organoaluminum cocatalyst compounds; D) optionally one or more internal electron donors; and E) optionally one or more selectivity control agents, a method of preparation and a method of use in polymerizing olefins is disclosed.

L'invention concerne une composition de catalyseur solide, insoluble dans un hydrocarbure, qui comprend : A) un complexe solide particulaire contenant des fractions d'au moins un élément du groupe constitué par le magnésium, un métal de transition du groupe 4 et un halogénure ; B) un ou plusieurs composés de 2-alkylpyridine .alpha.-amino-substitués ou .alpha.-imino- substitués ; C) un ou plusieurs composés de cocatalyseur d'organo-aluminium ; D) éventuellement un ou plusieurs donneurs d'électrons internes ; et E) éventuellement un ou plusieurs agents régulant la sélectivité. L'invention concerne aussi un procédé de préparation et un procédé d'utilisation de cette composition dans la polymérisation d'oléfines.

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