Polyurea coating compositions having faster dry times

C - Chemistry – Metallurgy – 09 – D

Patent

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C09D 175/02 (2006.01) C08G 18/10 (2006.01)

Patent

CA 2191015

The present invention relates to a coating composition for the preparation of a polyurea coating which contains a) an NCO prepolymer containing aromatically bound isocyanate groups and b) an aldimine corresponding to the formula X1-[N=CHCH(R1)(R2)]n wherein X represents an organic group which has a valency of n and is obtained by removing the amino groups from a cyclic organic polyamine having (cyclo)aliphatically-bound amino groups, R1 and R2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100°C or less, or R1 and R2 together with the .beta.-carbon atom form a cycloaliphatic or heterocyclic ring, and n represents an integer having a value of at least 2, in which components a) and b) are present in amounts sufficient to provide an equivalent ratio of isocyanate groups to aldimine groups of about 1.0:0.7 to 1.0:0.1.

Composition destinée à la préparation d'un revêtement de polyurée, renfermant : a) un prépolymère de NCO contenant des groupes isocyanate liés par des aromatiques; b) une aldimine correspondant à la formule X1-[N=CHCH(R1)(R2)]n; X représente un groupe organique de valence n, obtenu par élimination des groupes amino d'une polyamine organique cyclique, renfermant des groupes amino liés par des cycles aliphatiques; R1 et R2 peuvent être identiques ou différents et représenter des groupes organiques inertes vis-à-vis des groupes isocyanate à une température de 100 degrés C ou moins; ou R1 et R2 forment ensemble avec l'atome de carbone en bêta un noyau cycloaliphatique ou hétérocyclique; n est un entier supérieur ou égal à 2; dans cette composition, les constituants a) et b) sont présents en quantités suffisantes pour obtenir un rapport d'équivalents en groupes isocyanate/équivalents en groupes d'aldimine d'environ 1,0/0,7 à 1,0/0,1.

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