Organic microporous materials

Details Organic microporous materials Organic microporous materials

C - Chemistry, Metallurgy

08

G

C08G 73/06 (2006.01)

Patent

CA 2450786

A microporous network material comprises a rigid 3-dimensional network of planar porphyrinic macrocycles in which pyrrole residues of adjacent macrocycles are connected by rigid linkers which restrain these adjacent macrocycles such that their porphyrinic planes are in a non-co-planar orientation. Material in accordance with the invention generally have a surface area of at least 300M2g-1, e.g. in the range of 100-1000m2g-1. Preferred materials in accordance with the invention are phthalocyanine networks.

La présente invention concerne un matériau microporeux à structure en réseau comprenant un réseau tridimensionnel rigide de macrocycles porphyriniques bidimensionnels dans lesquels des résidus pyrrole de macrocycles adjacents sont connectés par des systèmes de liaison rigides qui limitent ces macrocycles adjacents de façon que leurs plans porphyriniques se trouvent selon une orientation non coplanaire. Le matériau selon cette invention présente généralement une surface d'au moins 300 m?2¿g?-1¿, par exemple entre 700 et 1000 m?2¿g?-1¿. Les matériaux préférés sont des réseaux de phthalocyanine.

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