Nickel-based dual catalyst systems effective in suppressing...

C - Chemistry – Metallurgy – 07 – D

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260/608.7, 260/2

C07D 295/023 (2006.01) C07C 209/14 (2006.01) C07C 213/02 (2006.01) C07C 217/28 (2006.01) C07D 295/027 (2006.01)

Patent

CA 2037227

NICKEL-BASED DUAL CATALYST SYSTEMS EFFECTIVE IN SUPPRESSING CARBON DIOXIDE FORMATION DURING DIETHYLENE GLYCOL AMINATION (D#80,931-F) ABSTRACT OF THE DISCLOSURE Disclosed is a process for simultaneously producing morpholine and DIGLYCOLAMINE? amine while suppressing C02 formation comprising the steps of: reacting diethylene glycol with ammonia in the presence of added hydrogen over a dual nickel-based catalyst comprising a nickel-copper-chromium oxide mix in combination with nickel-on-alumina, and isolating said morpholine compound and said DIGLYCOLAMINE? amine compound from the reaction products. CLK:pg EX9S/ 80931.app

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