Dimeric and tetrameric cyclopentadienyl group 6b metal...

C - Chemistry – Metallurgy – 08 – F

Patent

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C08F 4/78 (2006.01) C08F 4/69 (2006.01) C08F 10/00 (2006.01) C08F 4/639 (2006.01) C08F 4/6392 (2006.01)

Patent

CA 2127448

Disclosed is a catalyst system for the homopolymerization and copolymerization of alpha-olefins having 2-8 carbon atoms, said catalyst system comprising a dimeric or tetrameric cyclopentadienyl Group 6b metal compound in which the metal has an oxidation state of +2, said Group 6b metal compound being supported on an inorganic support. The catalyst system may also contain a Group 2 or Group 3 metal alkyl compound cocatalyst.

L'invention concerne un système de catalyseur pour l'homopolymérisation et la copolymérisation d'alpha-oléfines présentant 2 à 8 atomes de carbone, ledit système catalyseur contenant un composé métallique de groupe 6b à base de cyclopentadiényle dimère ou tétramère dans lequel le métal présente un état d'oxydation de 2+, le métal de groupe 6b étant placé sur un support inorganique. Ledit système de catalyseur peut également contenir un co-catalyseur à base d'alkyle de métal de groupe 2 ou 3.

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