Perfluorinated amide salts and their uses as ionic...

C - Chemistry – Metallurgy – 07 – F

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C07F 1/06 (2006.01) C07C 311/48 (2006.01) C07D 207/452 (2006.01) C07D 233/58 (2006.01) C07D 241/48 (2006.01) C07D 251/70 (2006.01) C07D 285/135 (2006.01) C07D 303/36 (2006.01) C07D 307/64 (2006.01) C07D 311/82 (2006.01) C07D 333/20 (2006.01) C07D 407/04 (2006.01) C07F 1/02 (2006.01) C07F 7/10 (2006.01) C07F 17/02 (2006.01) C08F 4/00 (2006.01) C08G 65/22 (2006.01) C08G 73/02 (2006.01) C08G 75/00 (2006.01) C08J 3/24 (2006.01) C09B 47/04 (2006.01) C09B 57/00 (2006.01) H01M 6/16 (2006.01) H01M 10/40 (2006.01)

Patent

CA 2248303

The invention relates to ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M?+m¿ in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO?+¿, an ammonium -NH¿4??+¿, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula R¿f?-SO¿x?-N?-¿Z, wherein R¿f? is a perfluorinated group, x is 1 or 2, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants, and the catalysis of various chemical reactions.

L'invention concerne des composés ioniques dans lesquels la charge anionique est délocalisée. Un composé de l'invention est constitué par une amide ou l'un de ses sels, comprenant une partie anionique associée à au moins une partie cationique M+m en nombre suffisant pour assurer la neutralité électronique de l'ensemble. M est un hydroxonium, un nitrosonium NO+, un ammonium -NH4+, un cation métallique ayant la valence m, un cation organique ayant la valence m ou un cation organo-métallique ayant la valence m. La partie anionique répond à la formule RF-SOx-N-Z dans laquelle RF est un groupe perfluoré, x est 1 ou 2, et Z est un substituant électroattracteur. Les composés sont utiles notamment pour les matériaux à conduction ionique, les matériaux à conduction électronique, les colorants et la catalyse de diverses réactions chimiques.

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