Gas phase olefin polymerization process

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

402/551, 252/52.

C08F 2/34 (2006.01) C08F 4/602 (2006.01) C08F 10/00 (2006.01)

Patent

CA 2039627

The present invention relates to an alpha-olefin prepolymer catalytically active in an alpha-olefin (co-)polymerization comprising a transition metal, an organometallic compound and an antistatic agent. The prepolymer can ba prepared by contacting the antistatic agent with a catalyst comprising the transition metal and the organometallic compound before or during an alpha-olefin prepolymerization. It can also be prepared by contacting the antistatic agent with an alpha-olefin prepolymer after a prepolymerization. It can also be prepared by a combination of the two methods. The prepolymer can be introduced into a gas phase (cc-)polymerization medium for preparing polyolefin directly in a dry powder form, with a reduced amount of sheeting and agglomerates.

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