Process for the continuously operated intermediate isolation...

C - Chemistry – Metallurgy – 07 – D

Patent

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C07D 301/12 (2006.01)

Patent

CA 2493273

The invention relates to a continuous method for the intermediate separation of the oxirane produced by the reaction of a hydroperoxide with an organic compound, characterised in that the product mixture generated during the synthesis is separated in a partition-wall column into a low-, middle and high- boiling fraction and the oxirane is taken off with the middle-boiling fraction at the side tap point of the column and the hydroperoxide is taken off with the high-boiling fraction from the bottom of the column.

L'invention concerne un procédé de séparation intermédiaire, guidé en continu, d'oxirane obtenu lors de la synthèse d'oxirane, par réaction d'un hydropéroxyde avec un composé organique. Le procédé selon l'invention est caractérisé en ce que le mélange de produit obtenu lors de la synthèse est séparé dans une colonne à membrane en une fraction à point d'ébullition bas, une fraction à point d'ébullition moyen, et une fraction à point d'ébullition élevé, l'oxirane est prélevé de la fraction à point d'ébullition moyen sur la zone d'extraction latérale de la colonne, et l'hydropéroxyde est prélevé de la fraction à point d'ébullition élevé avec le produit de bas de colonne.

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