Hydrogenation process

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 1/22 (2006.01) B01J 8/00 (2006.01) C07C 1/24 (2006.01) C10G 3/00 (2006.01)

Patent

CA 2665196

A process comprising reacting hydrogen and a reaction composition comprising a carboxylic acid and/or derivative thereof in a reactor to produce a reaction composition comprising one or more C1 compounds selected from one or more of carbon monoxide (CO), carbon dioxide (CO2) and methane (CH4), and one or more product hydrocarbons derived from the carboxylic acid and/or derivative thereof, wherein the molar ratio of C1 compounds produced by the reaction to the carboxylate groups present in the carboxylic acid and/or derivative thereof in the reaction composition is maintained above a value of 0,37 : 1.

La présente invention concerne un procédé comprenant la réaction de l'hydrogène et d'une composition de réaction comprenant un acide carboxylique et/ou un dérivé de celui-ci dans un réacteur de façon à produire une composition de réaction comprenant un ou plusieurs composés en C1 choisis parmi un ou plusieurs éléments parmi le monoxyde de carbone (CO),le dioxyde de carbone (CO2) et le méthane (CH4), et un ou plusieurs produits hydrocarbures dérivés de l'acide carboxylique et/ou d'un dérivé de celui-ci, le rapport molaire des composés en C1 produits par la réaction sur les groupes carboxylate présents dans l'acide carboxylique et/ou un dérivé de celui-ci dans la composition de réaction étant maintenu au-dessus d'une valeur de 0,37/1.

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