Synthesis of fluorinated dimethyl ethers

Details Synthesis of fluorinated dimethyl ethers Synthesis of fluorinated dimethyl ethers

C - Chemistry, Metallurgy

07

C

C07C 41/22 (2006.01) C07C 43/12 (2006.01)

Patent

CA 2052553

ABSTRACT OF THE DISCLOSURE A novel process is disclosed for the synthesis of fluorinated dimethyl ethers of the formula CF,HOCC1xFyH3-(x+y) wherein X and Y are each independently 0, 1, 2 or 3 and wherein the total X+Y is 2 or 3. The process involves chlorination of methyl difluoromethyl ether to form a chlorinated reaction product, including at least one compound of the formula CF,HOCH3-2C1, wherein z is 1, 2 or 3, which compound is then fluorinated, with or without separation from the chlorinated reaction product, to give a fluorinated reaction product including the aforementioned fluorinated dimethyl ethers.

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