Preparation of optically active hydrazines and amines

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 211/26 (2006.01) C07C 209/42 (2006.01) C07C 211/08 (2006.01) C07C 211/27 (2006.01) C07C 213/00 (2006.01) C07C 217/58 (2006.01) C07C 227/32 (2006.01) C07C 229/08 (2006.01) C07C 237/06 (2006.01) C07C 241/04 (2006.01) C07C 243/28 (2006.01) C07C 243/38 (2006.01) C07C 323/25 (2006.01) C07D 307/54 (2006.01) C07F 7/10 (2006.01)

Patent

CA 2131792

2131792 9319040 PCTABS00025 A process for the asymmetric hydrogenation of N-acylhydrazones to optically active N-acylhydrazines in the presence of a chiral phospholane catalyst complex, a process for the reductive N-N bond cleavage of N-acylhydrazine to amines with samarium diiodide, and a multistep process for converting keto group-bearing compounds to the corresponding optically active amino group-bearing compounds are disclosed.

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