B - Operations – Transporting – 01 – J
Patent
B - Operations, Transporting
01
J
B01J 31/22 (2006.01) B01J 31/24 (2006.01) C07F 7/08 (2006.01) C07F 9/50 (2006.01) C07F 15/00 (2006.01) C07F 17/00 (2006.01) C07F 17/02 (2006.01)
Patent
CA 2453886
Chiral organometallic compounds are provided which comprise certain non- symmetrically substituted cyclopentadiene complexed to a transition metal. The cyclopentadiene has a second coordinating group which also complexes the transition metal and is attached to the cyclopentadiene by means of a chiral connecting chain. Preferred transition metals include rhodium, ruthenium, iridium, cobalt, iron, manganese, chromium, tungsten, molybdenum, nickel, palladium, or platinum. These chiral organometallic compounds find use in asymmetric synthesis to produce chiral compounds.
L'invention concerne des composés organométalliques chiraux comprenant du cyclopentadiène substitué non symétriquement, complexé à un métal de transition. Le cyclopentadiène comprend un second groupe de coordination qui complexe également le métal de transition et qui est fixé au cyclopentadiène au moyen d'une chaîne de connexion chirale. Les métaux de transition utilisés de préférence sont le rhodium, le ruthénium, l'iridium, le cobalt, le fer, le manganèse, le chrome, le tungstène, le molybdène, le nickel, le palladium, ou le platine. On utilise ces composés organométalliques chiraux dans la synthèse asymétrique afin de produire des composés chiraux.
Avecia Limited
Smart & Biggar
LandOfFree
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