Method for preparing aminonitrile and diamine

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 253/30 (2006.01) C07C 209/48 (2006.01) C07C 211/12 (2006.01) C07C 255/24 (2006.01)

Patent

CA 2332613

The invention concerns a method for preparing aminonitrile and diamine by catalytic hydrogenating dinitrile. It consists of a method for preparing aminonitrile and diamine by catalytic hydrogenating aliphatic dinitrile having 3 to 12 carbon atoms, characterised in that the final reaction mixture, from which the catalyst has been previously separated, is acidified by adding a sufficient amount of a mineral or organic acid before it is subjected to an operation distilling the reaction products and the non-transformed dinitrile. The invention more particularly concerns the preparation of amino-6-capronitrile and hexamethylenediamine by hydrogenating adiponitrile. The amino-6-capronitrile can be hydrolysed in liquid phase or gaseous phase to lead to caprolactame. The hexamethylenediamine can be used in particular for preparing polyamide-66 by reaction with adipic acid.

La présente invention concerne un procédé de préparation d'aminonitrile et de diamine par hydrogénation catalytique de dinitrile. Elle consiste en un procédé de préparation d'aminonitrile et de diamine par hydrogénation catalytique de dinitrile aliphatique ayant de 3 à 12 atomes de carbone, caractérisé en ce que le mélange réactionnel final, dont le catalyseur a été préalablement séparé, est acidifé par addition d'une quantité suffisante d'un acide minéral ou organique, avant d'être soumis à une opération de distillation des produits de la réaction et du dinitrile non transformé. Elle concerne plus particulièrement la préparation d'amino-6 capronitrile et d'hexaméthylènediamine par hydrogénation de l'adiponitrile. L'amino-6 capronitrile peut être hydrolysé en phase liquide ou en phase gazeuse pour conduire au caprolactame. L'hexaméthylènediamine peut servir tout particulièrement à préparer le polyamide-65 par réaction avec l'acide adipique.

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